Complexation mechanism of cucurbit[6]uril with hexamethylene diammonium cations in saline solution

Literature Information

Publication Date 2014-10-06
DOI 10.1039/C4CP04200J
Impact Factor 3.676
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Abstract

Binding of cucurbit[6]uril (CB[6]) with the hexamethylene diammonium cation (HD2+) in the presence of sodium ions is elucidated at the atomic level. The most probable complex of CB[6] in saline solution is found to be CB[6]:Na+. A two-stage binding process of CB[6]:Na+ with HD2+ is proposed.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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