The invertible electrochemical properties and thermal response of a series of gel-type ionic liquids based on polyoxometalates

Literature Information

Publication Date 2014-10-01
DOI 10.1039/C4CP03673E
Impact Factor 3.676
Authors

Xuefei Wu, Yunyan Li, Qingyin Wu, Hong Ding, Wenfu Yan


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Abstract

A series of vanadium-substituted Dawson-structure POM-type ionic liquids, [TEAPS]7P2W17VO62 and [TEAPS]9P2W15V3O62, bearing sulfo-group grafted ammonium (TEAPS) cations and Dawson-type polyoxoanions have been formed which are reversible-thermal-response type gels. These gel-type compounds exhibit a phase transition from a quasi-solid gel phase to an isotropic sol phase. What's more, this series of hybrid compounds can undergo reversible electrochemical reactions in dimethyl formamide (DMF) owing to the reduction of the vanadium in POM anions as a simple anion, which is unlikely to happen in water solution because of water protonation.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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