Catalytic methylation of aromatic amines with formic acid as the unique carbon and hydrogen source

Literature Information

Publication Date 2014-09-24
DOI 10.1039/C4CC05908E
Impact Factor 6.222
Authors

Solène Savourey, Guillaume Lefèvre, Jean-Claude Berthet, Thibault Cantat


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Abstract

A novel methodology is presented for the direct methylation of amines, using formic acid as a unique source of carbon and hydrogen. Based on ruthenium(II) catalysts, the formation of the N–CH3 group proceeds via an efficient formylation/transfer hydrogenation pathway.

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