Quantitative formation of core cross-linked star polymersvia a one-pot two-step single electron transfer-living radical polymerization
Literature Information
Publication Date
2013-06-14
DOI
10.1039/C3PY00726J
Impact Factor
5.582
Authors
Edgar H. H. Wong, Anton Blencowe, Greg G. Qiao
View Original
Abstract
A novel and highly efficient one-pot two-step strategy towards core cross-linked star polymers based on single electron transfer-living radical polymerization (SET-LRP) is described. Macroinitiators with high end-group fidelity were generated at high monomer conversions prior to the addition of cross-linkable monomers in the same pot to induce the formation of star polymers. Quantitative (>99%) star formation is achieved without the purification of unreacted monomers or macroinitiators.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
Tris(2-ethylhexyl) 4,4',4''-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate
CAS Number:
88122-99-0
Molecular Formula:
C48H66N6O6
![3-[(4-Nitrobenzyl)oxy]-3-oxopropanoic Acid structure](https://static.chemtradehub.com/structs/773/77359-11-6-0d04.webp "3-[(4-Nitrobenzyl)oxy]-3-oxopropanoic Acid structure")
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