Nitroxide-catalyzed transition-metal-free aerobic oxidation processes

Literature Information

Publication Date 2013-08-20
DOI 10.1039/C3GC41459K
Impact Factor 10.182
Authors

Sebastian Wertz, Armido Studer


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Abstract

Advances in the field of transition-metal-free nitroxide-catalyzed aerobic oxidation processes are covered in this critical review. Along with the relevant physical properties of nitroxides, their application as oxidation catalysts by using dioxygen as a reagent or terminal oxidant will be discussed. The second part of the review focuses on the use of TEMPO-based nitroxides as catalysts for aerobic alcohol oxidation. Mechanistic studies will also be addressed (130 references).

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