“Release and catch” catalytic systems

Literature Information

Publication Date 2013-07-24
DOI 10.1039/C3GC41132J
Impact Factor 10.182
Authors

Michelangelo Gruttadauria, Francesco Giacalone, Renato Noto


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Abstract

In this perspective article the “release and catch” catalytic system concept is discussed. A “release and catch” catalytic system is prepared by non-covalent immobilization of the catalytic moiety on a suitable support, but differently from the usual non-covalently supported catalyst, the catalytic moiety is released in solution over the course of the reaction and it is recaptured at the end of the reaction. Such a “catalyst-sponge like” or “boomerang” system allows one to combine the benefits of homogeneous and heterogeneous catalysis and can be applied to organometallic-based catalysts, organocatalysts and metal-based catalysts.

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