Near-threshold photodissociation dynamics of CHCl3

Literature Information

Publication Date 2014-01-27
DOI 10.1039/C3CP55348E
Impact Factor 3.676
Authors


View Original

Abstract

Energy- and angle-resolved photofragment distributions for ground-state Cl (2P3/2) and spin–orbit excited Cl* (2P1/2) have been recorded using the velocity map imaging technique after photodissociation of chloroform at wavelengths of 193 and ∼235 nm. Translational energy distributions are rather broad and peak between 0.6 and 1.0 eV. The spin–orbit branching ratios [Cl*]/[Cl] are 1 and 0.3 at 193 and 235 nm, respectively, indicating the involvement of two or more excited state surfaces. Considering the anisotropy parameters and branching ratios collectively, we conclude that the reaction at 193 nm takes place predominantly on the 1Q1 surface, while the 3Q1 surface gains importance at lower dissociation energies around 235 nm.

Related Literature

Inside front cover

Cover

DOI: 10.1039/C7CP90017A

Effect of Ag and Pd promotion on CH4 selectivity in Fe(100) Fischer–Tröpsch catalysis

Jennifer Wilcox, David W. Ball

2017-01-23 Paper

DOI: 10.1039/C6CP07116C

Ionic liquids and deep eutectic solvents for lignocellulosic biomass fractionation

Dannie J. G. P. van Osch, Laura J. B. M. Kollau, Sari Asikainen, Marisa A. A. Rocha

2016-12-02 Perspective

DOI: 10.1039/C6CP07499E

Suitability of N-propanoic acid spiropyrans and spirooxazines for use as sensitizing dyes in dye-sensitized solar cells

Noah M. Johnson, Yuriy Y. Smolin, Daniel Hagaman, Masoud Soroush, Kenneth K. S. Lau, Hai-Feng Ji

2017-01-04 Paper

DOI: 10.1039/C6CP07853B

Front cover

Cover

DOI: 10.1039/C7CP90034A

Ligand non-innocence and strong correlation in manganese superoxide dismutase mimics

Alexandra R. McIsaac, David A. Mazziotti

2017-01-26 Paper

DOI: 10.1039/C6CP07563K

The decomposition of benzenesulfonyl azide: a matrix isolation and computational study

Guohai Deng, Xuelin Dong, Qifan Liu, Dingqing Li, Hongmin Li, Qiao Sun, Xiaoqing Zeng

2017-01-11 Paper

DOI: 10.1039/C6CP08125H

Triplet exciton dissociation and electron extraction in graphene-templated pentacene observed with ultrafast spectroscopy

Thomas J. McDonough, Lushuai Zhang, Susmit Singha Roy, Nicholas M. Kearns, Michael S. Arnold, Martin T. Zanni

2017-01-23 Paper

DOI: 10.1039/C6CP06454J

Understanding the influence of Mg doping for the stabilization of capacity and higher discharge voltage of Li- and Mn-rich cathodes for Li-ion batteries

Prasant Kumar Nayak, Judith Grinblat, Elena Levi, Mikhael Levi, Boris Markovsky, Doron Aurbach

2017-01-20 Paper

DOI: 10.1039/C6CP07383B

You might also like

Compound Q&A

What are the main uses of (5-Sulfamoyl-3-pyridinyl)boronic acid (CAS: 951233-61-7)?

(5-Sulfamoyl-3-pyridinyl)boronic acid is primarily used in chemical synthesis, p...

951233-61-7(5-Sulfamoyl-3-pyrid...
Compound Q&A

How is Benzyl 2-methyl-2-(methylsulfonyl)-4-pentenoate (CAS: 1942858-50-5) typically synthesized?

Benzyl 2-methyl-2-(methylsulfonyl)-4-pentenoate is typically synthesized via est...

1942858-50-5Benzyl 2-methyl-2-(m...
Compound Q&A

What precautions should be taken when handling 8-Fluoroquinolin-6-ol (CAS: 209353-22-0)?

When handling 8-Fluoroquinolin-6-ol (CAS: 209353-22-0), it is important to use p...

209353-22-08-Fluoroquinolin-6-o...
Compound Q&A

What are the physical and chemical properties of 1,3-Dibromo-5-(2-methyl-2-propanyl)benzene (CAS: 129316-09-2)?

1,3-Dibromo-5-(2-methyl-2-propanyl)benzene (CAS: 129316-09-2) is a crystalline c...

129316-09-21,3-Dibromo-5-(2-met...
Compound Q&A

What industries use Ethyl 7-chloro-4-oxo-1-(1,3-thiazol-2-yl)-1,4-dihydro-1,8-naphthyridine-3-carboxylate (CAS: 174726-87-5)?

Ethyl 7-chloro-4-oxo-1-(1,3-thiazol-2-yl)-1,4-dihydro-1,8-naphthyridine-3-carbox...

174726-87-5Ethyl 7-chloro-4-oxo...
Compound Q&A

What precautions should be taken when handling Delta-7-Avenasterol (CAS: 23290-26-8)?

When handling Delta-7-Avenasterol (CAS: 23290-26-8), it is important to wear app...

23290-26-8Delta-7-Avenasterol
872992-20-6N-({(5R)-3-[3-Fluoro...
Compound Q&A

What precautions should be taken when handling 2-Methyl-2-proanyl 4-[(2-aminophenyl)amino]-1-piperidinecarboxylate (CAS: 79099-00-6)?

When handling 2-Methyl-2-proanyl 4-[(2-aminophenyl)amino]-1-piperidinecarboxylat...

79099-00-62-Methyl-2-propanyl ...
Compound Q&A

What is N-Methyl-4-chlorobenzylamine hydrochloride (CAS: 65542-24-7)?

N-Methyl-4-chlorobenzylamine hydrochloride (CAS: 65542-24-7) is a organic compou...

65542-24-7N-Methyl-4-chloroben...
Compound Q&A

Is [2-(Dodecyloxy)ethoxy]acetic acid (CAS: 27306-90-7) safe?

[2-(Dodecyloxy)ethoxy]acetic acid (CAS: 27306-90-7) is generally considered safe...

27306-90-7[2-(Dodecyloxy)ethox...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.