Estimation of the refractive indices of imidazolium-based ionic liquids using their polarisability values

Literature Information

Publication Date 2013-10-28
DOI 10.1039/C3CP53685H
Impact Factor 3.676
Authors

Pablo Díaz-Rodríguez, John C. Cancilla, Natalia V. Plechkova, Gemma Matute, Kenneth R. Seddon, José S. Torrecilla


View Original

Abstract

Statistical models have been used to estimate the refractive index of 72 imidazolium-based ionic liquids using the electronic polarisability of their ions as the data for two different mathematical approaches: artificial neural networks, in the form of multi-layer perceptrons, and multiple linear regression models. Although the artificial neural networks and linear models have been able to accomplish this task, the multi-layer perceptron model has been shown to be a more accurate method, thanks to its ability of determining non-linear relationships between different dependent variables. Additionally, it is clear that the multiple linear regression presents a systematic deviation in the estimated refractive index values, which confirms that it is an inappropriate model for this system.

Related Literature

Correction: A tutorial on asymmetric electrocatalysis

Jonas Rein, Samson B. Zacate, Kaining Mao, Song Lin

2023-12-05 Correction

DOI: 10.1039/D3CS90096G

Electron transport through supercrystals of atomically precise gold nanoclusters: a thermal bi-stability effect

Tatsuya Higaki, Jake C. Russell, Daniel W. Paley, Xavier Roy, Rongchao Jin

2023-11-09 Edge Article

DOI: 10.1039/D3SC02753H

Front cover

2023-11-15 Cover

DOI: 10.1039/D3SC90221H

Strengths of covalent bonds in LnO2 determined from O K-edge XANES spectra using a Hubbard model

Wayne W. Lukens, Jr, Stefan G. Minasian, Corwin H. Booth

2023-11-03 Edge Article

DOI: 10.1039/D3SC03304J

Pursuing excitonic energy transfer with programmable DNA-based optical breadboards

Divita Mathur, Sebastián A. Díaz, Ryan D. Pensack, Bernard Yurke, Austin Biaggne, Joseph S. Melinger, William B. Knowlton, Igor L. Medintz

2023-10-24 Review Article

DOI: 10.1039/D0CS00936A

Chalcogen bonding catalysis

Govindasamy Sekar, Vysakh Venugopalan Nair, Jieping Zhu

2023-12-07 Tutorial Review

DOI: 10.1039/D3CS00503H

Front cover

2023-12-11 Cover

DOI: 10.1039/D3CS90097E

Recent progress in SERS monitoring of photocatalytic reactions

Xinlu Zheng, Ziwei Ye, Zeeshan Akmal, Chun He, Jinlong Zhang, Lingzhi Wang

2024-01-02 Review Article

DOI: 10.1039/D3CS00462G

You might also like

Compound Q&A

What are the main uses of (3alpha,5alpha)-3-Hydroxypregnane-11,20-dione (CAS: 23930-19-0)?

(3alpha,5alpha)-3-Hydroxypregnane-11,20-dione is primarily used in the pharmaceu...

23930-19-0(3alpha,5alpha)-3-Hy...
Compound Q&A

What is the market or research trend for 4-Amino-6-chloro-2-pyridinecarboxylic acid (CAS: 546141-56-4)?

The market for 4-Amino-6-chloro-2-pyridinecarboxylic acid (CAS: 546141-56-4) is ...

546141-56-44-Amino-6-chloro-2-p...
Compound Q&A

Are there alternatives to (2-Benzoylethyl)trimethylammonium chloride (CAS: 24472-88-6) in synthesis?

Alternatives to (2-Benzoylethyl)trimethylammonium chloride (CAS: 24472-88-6) in ...

24472-88-6(2-Benzoylethyl)trim...
Compound Q&A

Is N-[4-Nitro-3-(trifluoromethyl)phenyl]acetamide (CAS: 393-12-4) safe?

N-[4-Nitro-3-(trifluoromethyl)phenyl]acetamide (CAS: 393-12-4) is generally safe...

393-12-4N-[4-Nitro-3-(triflu...
Compound Q&A

Are there alternatives to N,N'-Bis(3-aminopropyl)-1,3-propanediamine (CAS: 4605-14-5) in synthesis?

There are alternatives to N,N'-Bis(3-aminopropyl)-1,3-propanediamine (CAS: 4605-...

4605-14-5N,N'-Bis(3-aminoprop...
Compound Q&A

What precautions should be taken when handling Aluminium trihexadecanoate (CAS: 555-35-1)?

When handling Aluminium trihexadecanoate, it is important to use appropriate per...

555-35-1Aluminium trihexadec...
Compound Q&A

What is (1,1-Dioxido-3-oxo-1,2-benzothiazol-2(3H)-yl)acetic acid (CAS: 52188-11-1)?

(1,1-Dioxido-3-oxo-1,2-benzothiazol-2(3H)-yl)acetic acid is a chemical compound ...

52188-11-1(1,1-Dioxido-3-oxo-1...
Compound Q&A

Are there alternatives to 5,5-dimethyloxolan-2-one (CAS: 3123-97-5) in synthesis?

Several alternatives to 5,5-dimethyloxolan-2-one (CAS: 3123-97-5) can be used in...

3123-97-55,5-dimethyloxolan-2...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.