Velocity map imaging of ion–molecule reactions

Literature Information

Publication Date 2013-10-17
DOI 10.1039/C3CP53405G
Impact Factor 3.676
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Abstract

Velocity map imaging has been a highly successful method to study molecular and chemical dynamics. In recent years, we have combined this method with ion–molecule reactive scattering experiments and studied the dynamics of several fundamental ion–molecule reactions. Here, we describe the main components of the experiment and discuss the most important limitations to the obtainable imaging resolution. Then, results from our group are presented for both cation and anion–molecule reactions. Specifically, the charge transfer reaction Ar+ + N2 and the nucleophilic substitution reaction X− + CH3I (X = Cl, F, OH), including recent results on micro-solvated water cluster anions, are reviewed. Furthermore, new and open questions and several future directions for research on ion–molecule reactive scattering are mapped out.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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