Photodissociation of CO2 between 13.540 eV and 13.678 eV

Literature Information

Publication Date 2013-10-11
DOI 10.1039/C3CP53250J
Impact Factor 3.676
Authors

Yu Song, Hong Gao, Yih Chung Chang, Zhou Lu, C. Y. Ng, William M. Jackson


View Original

Abstract

Photodissociation of CO2 is investigated between 13.540 eV and 13.678 eV using the time-sliced velocity-mapped ion imaging (TSVMI) apparatus that is combined with one-color and two-color pump–probe VUV + VUV and VUV + UV detection schemes by probing oxygen fragments at different levels. Several CO2 dissociation channels are directly observed from the ion images, namely CO(X 1Σ+) + O(1D), CO(X 1Σ+) + O(1S), CO(a 3Π) + O(3P), CO(a 3Π) + O(1D), CO(a′ 3Σ+) + O(3P), CO(d 3Δ) + O(3P) and CO(e 3Σ−) + O(3P), whereas no CO(X 1Σ+) + O(3P) production has been found. The product kinetic energy distributions of these channels are reported for the first time. Possible dissociation mechanisms have been discussed based upon the product vibrational and rotational distributions.

Related Literature

Cyclic voltammetry and chronoamperometry: mechanistic tools for organic electrosynthesis

Mohammad Rafiee, Dylan J. Abrams, Luana Cardinale, Zachary Goss, Shannon S. Stahl

2023-12-05 Tutorial Review

DOI: 10.1039/D2CS00706A

Inside front cover

2024-01-22 Cover

DOI: 10.1039/D4CS90005G

Contents list

2023-12-11 Front/Back Matter

DOI: 10.1039/D3CS90099A

Bioorthogonal chemistry for prodrug activation in vivo

Siyong Shen, Pengwei Sun, Zhi Gu, Yifei Bai, Xianglin Wang

2023-10-31 Review Article

DOI: 10.1039/D2CS00889K

Back cover

2024-01-22 Cover

DOI: 10.1039/D4CS90007C

Chemical technology principles for selective bioconjugation of proteins and antibodies

Preeti Chauhan, Ragendu V., Mohan Kumar, Rajib Molla, Surya Dev Mishra, Sneha Basa, Vishal Rai

2023-12-14 Review Article

DOI: 10.1039/D3CS00715D

Front cover

2024-01-22 Cover

DOI: 10.1039/D4CS90004A

Asymmetric catalysis with FLPs

2023-11-14 Review Article

DOI: 10.1039/D3CS00701D

Back cover

2023-11-22 Cover

DOI: 10.1039/D3SC90229C

Nanoscale engineering of solid-state materials for boosting hydrogen storage

Yudong Xue

2023-12-19 Review Article

DOI: 10.1039/D3CS00706E

You might also like

Compound Q&A

What are the main uses of (3alpha,5alpha)-3-Hydroxypregnane-11,20-dione (CAS: 23930-19-0)?

(3alpha,5alpha)-3-Hydroxypregnane-11,20-dione is primarily used in the pharmaceu...

23930-19-0(3alpha,5alpha)-3-Hy...
Compound Q&A

What is the market or research trend for 4-Amino-6-chloro-2-pyridinecarboxylic acid (CAS: 546141-56-4)?

The market for 4-Amino-6-chloro-2-pyridinecarboxylic acid (CAS: 546141-56-4) is ...

546141-56-44-Amino-6-chloro-2-p...
Compound Q&A

Are there alternatives to (2-Benzoylethyl)trimethylammonium chloride (CAS: 24472-88-6) in synthesis?

Alternatives to (2-Benzoylethyl)trimethylammonium chloride (CAS: 24472-88-6) in ...

24472-88-6(2-Benzoylethyl)trim...
Compound Q&A

Is N-[4-Nitro-3-(trifluoromethyl)phenyl]acetamide (CAS: 393-12-4) safe?

N-[4-Nitro-3-(trifluoromethyl)phenyl]acetamide (CAS: 393-12-4) is generally safe...

393-12-4N-[4-Nitro-3-(triflu...
Compound Q&A

Are there alternatives to N,N'-Bis(3-aminopropyl)-1,3-propanediamine (CAS: 4605-14-5) in synthesis?

There are alternatives to N,N'-Bis(3-aminopropyl)-1,3-propanediamine (CAS: 4605-...

4605-14-5N,N'-Bis(3-aminoprop...
Compound Q&A

What precautions should be taken when handling Aluminium trihexadecanoate (CAS: 555-35-1)?

When handling Aluminium trihexadecanoate, it is important to use appropriate per...

555-35-1Aluminium trihexadec...
Compound Q&A

What is (1,1-Dioxido-3-oxo-1,2-benzothiazol-2(3H)-yl)acetic acid (CAS: 52188-11-1)?

(1,1-Dioxido-3-oxo-1,2-benzothiazol-2(3H)-yl)acetic acid is a chemical compound ...

52188-11-1(1,1-Dioxido-3-oxo-1...
Compound Q&A

Are there alternatives to 5,5-dimethyloxolan-2-one (CAS: 3123-97-5) in synthesis?

Several alternatives to 5,5-dimethyloxolan-2-one (CAS: 3123-97-5) can be used in...

3123-97-55,5-dimethyloxolan-2...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.