Syntheses of three members of A(II)M(IV)(PO4)2: luminescence properties of PbGe(PO4)2 and its Eu3+-doped powders

Literature Information

Publication Date 2013-07-05
DOI 10.1039/C3CE40936H
Impact Factor 3.545
Authors

Wei-Long Zhang, Chen-Sheng Lin, Zhang-Zhen He, Hao Zhang, Zhong-Zhen Luo, Wen-Dan Cheng


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Abstract

We present here the syntheses and optical properties of three phosphates, namely, AM(PO4)2 (A = Pb2+, M = Ti, Ge; A = Sr2+, M = Ge). Thereinto, PbGe(PO4)2 features a strong green broad-band emission peaking at 508 nm at room temperature when excited by UV irradiation. Its luminescence properties, decay time and Commission Internationale de l'Éclairage (CIE) chromaticity index have been determined. Additionally, the photoluminescent properties of its Eu3+-doped powders have also been investigated. Finally, the calculations of energy band structure and density of states have been performed to construct an available model to explain a possible mechanism of electron transition.

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