Mono- and di-cyclocarbonate telechelic polyolefins synthesized from ROMP using glycerol carbonate derivatives as chain-transfer agents
Literature Information
Publication Date
2013-01-08
DOI
10.1039/C2PY21141F
Impact Factor
5.582
Authors
Liana Annunziata, Stéphane Fouquay, Guillaume Michaud, Frédéric Simon, Sophie M. Guillaume, Jean-François Carpentier
View Original
Abstract
The ring-opening metathesis polymerization (ROMP) of cyclooctene (COE) has been achieved with Grubbs 2nd generation ruthenium catalyst in the presence of vinyl or acryloyl derivatives of glycerol carbonate. Such asymmetric chain-transfer agents enabled the synthesis in high yields of α-cyclocarbonate,ω-vinyl-poly(cyclooctene) (PCOE) and, more rewardingly, of the highly valuable α,ω-dicyclocarbonate telechelic PCOE.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![2-{3-[4-(3-Chlorophenyl)-1-piperazinyl]propyl}[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one hydrochloride (1:1) structure](https://static.chemtradehub.com/structs/253/25332-39-2-496e.webp "2-{3-[4-(3-Chlorophenyl)-1-piperazinyl]propyl}[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one hydrochloride (1:1) structure")
2-{3-[4-(3-Chlorophenyl)-1-piperazinyl]propyl}[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one hydrochloride (1:1)
CAS Number:
25332-39-2
Molecular Formula:
C19H23Cl2N5O
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