Reduction of the rate retardation effect in bulk RAFT radical polymerization under an externally applied magnetic field

Literature Information

Publication Date 2013-01-07
DOI 10.1039/C2PY20998E
Impact Factor 5.582
Authors

Ling Lv, Wenxuan Wu, Gang Zou, Qijin Zhang


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Abstract

Bulk RAFT radical polymerization of (2-cyano-2-propyl) dithiobenzoate/styrene was performed under an externally applied magnetic field (EAMF) to explore a universal method to reduce the rate retardation effect. Under a tunable EAMF, the rate of RAFT polymerization is enhanced and the optimal EAMF intensity is found to be 0.1 T. Experimental observation in this work offers an efficient method for enhancing the rate of various RAFT radical polymerizations.

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Polymer Chemistry

Polymer Chemistry
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