Microporous organic polymers synthesized by self-condensation of aromatic hydroxymethyl monomers
Literature Information
Publication Date
2012-11-13
DOI
10.1039/C2PY20914D
Impact Factor
5.582
Authors
Yali Luo, Shoucun Zhang, Yunxiang Ma, Wei Wang, Bien Tan
View Original
Abstract
Two hypercross-linked polymer networks have been synthesized by the self-condensation of bishydroxymethyl monomer, 1,4-benzenedimethanol (BDM), and monohydroxymethyl compound, benzyl alcohol (BA). This is different from the previous reports where multifunctional monomers or cross-linkers are crucial for constructing the porous polymer networks. N2 sorption isotherms for the polymers show that both materials are predominantly microporous with Brunauer–Emmett–Teller (BET) surface areas of 847 m2 g−1 for HCP–BDM and 742 m2 g−1 for HCP–BA. A network based on BA can also store a significant amount of CO2 (8.46 wt%) and H2 (0.97 wt%) at 1.0 bar, and at 273 K and 77 K respectively, despite its relatively modest surface area. Based on these results, this study opens up the possibility of synthesizing porous materials using monofunctional monomers.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
Tris(2-ethylhexyl) 4,4',4''-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate
CAS Number:
88122-99-0
Molecular Formula:
C48H66N6O6
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