Recent progress on phosphonate vinyl monomers and polymers therefore obtained by radical (co)polymerization
Literature Information
Publication Date
2011-09-23
DOI
10.1039/C1PY00276G
Impact Factor
5.582
Authors
G. David, C. Negrell-Guirao, F. Iftene, B. Boutevin, K. Chougrani
View Original
Abstract
This review paper gathers almost one hundred recent publications devoted to the synthesis and the free radical (co)polymerization of phosphonate vinyl monomers. Different synthetic approaches are discussed to introduce the phosphonate moieties into vinyl monomers, focusing especially on recent advances. Allyl-type, vinyl-type, styrenic-type and (meth)acrylic-type monomers bearing phosphonate groups (i.e. either mono or bisphosphonate) are considered with a special care about their reactivity in free radical (co)polymerization. It is shown that depending on the position of the phosphonate moieties the reactivity of the vinyl monomers is thus modified. For instance, free radical polymerization of vinyl phosphonate monomers is mainly dominated by transfer reactions, whereas the propagation rate of para-vinylbenzyl phosphonate monomers is enhanced by the phosphonate group. According to the structure of the phosphonate-bearing (co)polymers, the resulting properties are also investigated.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![(3aR,7R,7aR)-2,2-Diethyl-3a,6,7,7a-tetrahydro-7-[(methylsulfonyl)oxy]-1,3-benzodioxole-5-carboxylic Acid Ethyl Ester structure](https://static.chemtradehub.com/structs/204/204254-90-0-7172.webp "(3aR,7R,7aR)-2,2-Diethyl-3a,6,7,7a-tetrahydro-7-[(methylsulfonyl)oxy]-1,3-benzodioxole-5-carboxylic Acid Ethyl Ester structure")
(3aR,7R,7aR)-2,2-Diethyl-3a,6,7,7a-tetrahydro-7-[(methylsulfonyl)oxy]-1,3-benzodioxole-5-carboxylic Acid Ethyl Ester
CAS Number:
204254-90-0
Molecular Formula:
C15H24O7S
Phenanthro(3,2-b)furan-6(2H)-one, 1,8,9,11b-tetrahydro-7,11-dihydroxy-3,4,9,11b-tetramethyl-, cis-
CAS Number:
99624-92-7
Molecular Formula:
C20H22O4
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