Formation of nitric oxide and nitrous oxide in electron-irradiated H218O/N2 ice mixtures—evidence for the existence of free oxygen atoms in interstellar and solar system analog ices

Literature Information

Publication Date 2011-05-17
DOI 10.1039/C1CP20528E
Impact Factor 3.676
Authors

Y. Seol Kim


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Abstract

We investigated the irradiation of low temperature H218O/N2 ice mixtures with energetic electrons in an ultrahigh vacuum chamber. The newly formed species, such as nitric oxide (N18O), nitrous oxide (NN18O), hydrogen peroxide (H218O2) and hydrazine (N2H4), were identified in the experiments with infrared absorption spectroscopy and mass spectrometry. The results suggest that the unimolecular decomposition of water molecules within water ices at 10 K can lead to the formation of transient, suprathermal oxygen atoms. These oxygen atoms may play an important role in the formation of oxygen-containing biomolecules such as amino acids and sugar, as well as the decomposition of the biomolecules in the ices.

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