Shared solvation of sodium ions in alcohol–water solutions explains the non-ideality of free energy of solvation
Literature Information
Kathrin M. Lange, Ulf Bergmann, Kai F. Hodeck, René Könnecke, Ulrich Schade
In order to explain the discrepancies between theories and experiments regarding the non-ideality in the free energy of solvation, here we present a microscopic picture of sodium ions dissolved in water–alcohol mixed solvents. We used X-ray absorption spectroscopy to probe the K-edge of sodium ions in mixed solvents of water and alcohols (methanol, ethanol) and in the respective pure solvents. In the mixed solvents a shared solvation of the sodium ions is observed. We find that specifically the water component plays a key role in stabilizing the solvation shell in mixed solvents, which was revealed by a selective photochemical process occurring only in the pure alcohol solvents.
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