Properties of ionic liquids on Au surfaces: non-conventional anion exchange reactions with carbonate
Literature Information
Mathieu Ratel, Mathieu Branca, Julien Breault-Turcot, Sandy Shuo Zhao, Pierre Chaurand, Andreea R. Schmitzer, Jean-Francois Masson
A simple anion metathesis in diluted aqueous carbonate at room temperature affords 1-(12-mercaptododecyl)-3-methyl-imidazolium carbonate (MDMI-HCO3) from MDMI salts self-assembled on gold films and nanoparticles. The properties of MDMI-SAM differ from MDMI in solution, for which the anion exchange reaction does not proceed.
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