Crossed molecular beam ion-imaging study of the Cl + SiH4 → HCl + SiH3 reaction: product vibrational state-to-state correlation

Literature Information

Publication Date 2010-06-25
DOI 10.1039/B927455C
Impact Factor 3.676
Authors

Guorong Wu, Weiqing Zhang, Huilin Pan, Quan Shuai, Jiayue Yang, Bo Jiang, Dongxu Dai, Xueming Yang


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Abstract

The dynamics of the Cl + SiH4 → HCl + SiH3 reaction has been studied using the crossed molecular beam technique with slice imaging. The ion images of the silyl radical (SiH3) product from the Cl + SiH4 reaction were recorded at different collision energies, using the (2 + 1) resonance enhanced multi-photon ionization (REMPI) technique. The product velocity and angular distributions of this reaction were determined from the recorded images. The vibrational state-to-state correlation of the relative population between the two reaction products, SiH3 and HCl, was also determined. Finally, the Cl + SiH4 results are compared with that of the F + SiH4 reaction.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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