Enantiomerically pure P-chiral phosphinoselenoic chlorides: inversion of configuration at the P-chirogenic center in the synthesis and reaction of these substances

Literature Information

Publication Date 2005-07-13
DOI 10.1039/B507755A
Impact Factor 6.222
Authors

Tsutomu Kimura, Toshiaki Murai


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Abstract

Reaction of diastereomerically pure phosphinoselenoic acid salts with oxalyl chloride leads to enantiomerically pure P-chiral phosphinoselenoic chlorides with inversion of configuration at phosphorus; one of these chlorides is converted to a phosphinoselenothioic acid salt with a high degree of enantioselectivity.

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