Electromagnetic field effects on binary dimethylimidazolium-based ionic liquid/water solutions

Literature Information

Publication Date 2009-09-15
DOI 10.1039/B910462C
Impact Factor 3.676
Authors

Niall J. English, Damian A. Mooney


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Abstract

The non-thermal effects of electromagnetic fields in the microwave to far-infrared frequency on neat dimethylimidazolium chloride and triflate salts and their binary mixtures with water have been investigated by means of non-equilibrium molecular dynamics simulation. Significant alterations in dipole alignment and molecular mobility were found vis-à-vis zero-field conditions for mixtures of varying composition. Results indicate that the dimethylimidazolium and triflate ions respond most significantly to frequencies much lower than that of water in terms of dipole alignment and molecular mobility, and this was rationalized. in terms of dipole moment magnitudes, rotational inertia and translational field response.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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