Large H2 storage capacity of a new polyhedron-based metal–organic framework with high thermal and hygroscopic stability

Literature Information

Publication Date 2009-07-24
DOI 10.1039/B909250A
Impact Factor 6.222
Authors

Seunghee Hong, Minhak Oh, Mira Park, Ji Woong Yoon, Jong-San Chang, Myoung Soo Lah


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Abstract

Two metal–organic frameworks (MOFs) based on metal–organic cuboctahedra were prepared using a rigid C3 symmetric ligand, where Zn polyhedron-based MOF (PMOF-2(Zn)) did not show any significant gas sorption behavior, whereas the isostructural Cu polyhedron-based MOF (PMOF-2(Cu)) showed a large surface area of ∼4180 m2 g−1, high hydrothermal stability, and very promising H2 sorption properties.

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