Interactions and dynamics in electrolyte solutions by dielectric spectroscopy

Literature Information

Publication Date 2009-07-02
DOI 10.1039/B906555P
Impact Factor 3.676
Authors

Richard Buchner, Glenn Hefter


View Original

Abstract

Despite its immense abilities to quantify many aspects of ion–ion and ion–solvent interactions, dielectric relaxation spectroscopy (DRS) has long been neglected as a tool for the investigation of the structure and dynamics of electrolyte solutions. The reasons for this are briefly discussed and it is shown that many of the difficulties associated with this technique have been overcome in recent years by technological developments. Representative applications of DRS to the investigation of ion solvation and ion association in electrolyte solutions of chemical, industrial, geochemical and biological interest, including room temperature ionic liquids and polyelectrolyte systems, are discussed. The advantages of linking DRS measurements to information obtained from other experimental techniques and from computer simulations are highlighted.

Related Literature

Simulation of intermediate transport in nanoscale scaffolds for multistep catalytic reactions

Erica Earl, Scott Calabrese Barton

2017-05-24 Paper

DOI: 10.1039/C7CP00239D

Electrode potential dependent desolvation and resolvation of germanium(100) in contact with aqueous perchlorate electrolytes

Fang Niu, Rainer Schulz, Arcesio Castañeda Medina, Rochus Schmid

2017-05-10 Paper

DOI: 10.1039/C6CP08908A

Editorial of the PCCP themed issue on “Physical Chemistry for Life Sciences”

Christoph van Wüllen, Kirsten Schwing, Christoph Riehn, Markus Gerhards

2017-04-19 Editorial

DOI: 10.1039/C7CP90069D

Ab initio calculation of the attempt frequency of oxygen diffusion in pure and samarium doped ceria

Julius Koettgen, Tobias Zacherle

2017-03-24 Paper

DOI: 10.1039/C6CP04802A

Rovibrational spectroscopic constants of the interaction between ammonia and metallo-phthalocyanines: a theoretical protocol for ammonia sensor design

Daniel F. S. Machado, Valter H. Carvalho-Silva, Leonardo G. Paterno, Heibbe Cristhian B. de Oliveira

2017-02-15 Paper

DOI: 10.1039/C6CP07900H

Unusual molecular mechanism behind the thermal response of polypeptoids in aqueous solutions

Jianbo Ma, Sunting Xuan, Abby C. Guerin, Tianyi Yu, Donghui Zhang, Daniel G. Kuroda

2017-04-04 Paper

DOI: 10.1039/C6CP08536A

Intracellular-molecular changes in plasma-irradiated budding yeast cells studied using multiplex coherent anti-Stokes Raman scattering microscopy

Ryo Furuta, Naoyuki Kurake, Kenji Ishikawa, Keigo Takeda, Hiroshi Hashizume, Hiroki Kondo, Takayuki Ohta, Masafumi Ito, Makoto Sekine, Masaru Hori

2017-04-27 Communication

DOI: 10.1039/C7CP00489C

Understanding nanoparticle porosity via nanoimpacts and XPS: electro-oxidation of platinum nanoparticle aggregates

Xue Jiao, Eden E. L. Tanner, Stanislav V. Sokolov, Robert G. Palgrave, Neil P. Young, Richard G. Compton

2017-05-10 Paper

DOI: 10.1039/C7CP01737E

You might also like

Compound Q&A

How should waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3) be handled?

Waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3...

898825-89-3N-Methoxy-N-methyl-1...
Compound Q&A

How should N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine (CAS: 1318338-47-4) be stored?

N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine should be stored in a tightly sealed c...

1318338-47-4N-(4-Biphenylyl)dibe...
Compound Q&A

What is the market or research trend for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1)?

The market for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1) is...

1713-07-13-Acetamido-5-amino-...
Compound Q&A

How should Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) be stored?

Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) ...

61820-03-9Benzyl 2-O-acetyl-3,...
Compound Q&A

What regulatory guidelines apply to 2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3)?

2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3) is regulated under the Glob...

438050-52-32-Ethylpiperazine di...
Compound Q&A

What regulatory guidelines apply to 1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 119462-56-5)?

1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 11946...

119462-56-51,1'-[1,3-Phenyleneb...
Compound Q&A

Are there alternatives to 5-Fluoro-2-(1-pyrrolidinyl)pyridine (CAS: 1287217-79-1) in synthesis?

Several alternatives can be used in the synthesis of 5-Fluoro-2-(1-pyrrolidinyl)...

1287217-79-15-Fluoro-2-(1-pyrrol...
Compound Q&A

What precautions should be taken when handling 6-Bromoimidazo[1,2-a]pyridin-8-amine (CAS: 676371-00-9)?

When handling 6-Bromoimidazo[1,2-a]pyridin-8-amine, it is important to wear appr...

676371-00-96-Bromoimidazo[1,2-a...
Compound Q&A

Are there alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochloride (CAS: 1049740-22-8) in synthesis?

Alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochlo...

1049740-22-8(2S,4R)-4-(4-Nitrobe...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.