A double cubane structure in organoplatinum(iv) chemistry
Literature Information
Publication Date
2009-02-18
DOI
10.1039/B822683K
Impact Factor
6.222
Authors
Muhieddine S. Safa, Michael C. Jennings, Richard J. Puddephatt
View Original
Abstract
The reaction of [PtMe2(dpe)], dpe = 1,2-di-2-pyridylethane, with hydrogen peroxide occurs with ligand loss to give [{PtMe2(OH)2}n], but the reaction mixture then slowly yields crystals of [{PtMe3OH·PtMe2(OH)2}2][PtMe2(CO3)(dpe)]2, in which the central cluster has an unexpected structure based on a face-bridged double cubane.
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CAS Number:
874289-09-5
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