A tris(alkyl)yttrium compound containing six β-agostic Si–H interactions

Literature Information

Publication Date 2008-12-12
DOI 10.1039/B818630H
Impact Factor 6.222
Authors

KaKing Yan, Andrew V. Pawlikowski, Chris Ebert, Aaron D. Sadow


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Abstract

The new homoleptic rare earth compound [Y(C(SiHMe2)3)3] (2) is prepared in 82% yield by salt metathesis of YCl3 and 3 equivalents of [KC(SiHMe2)3] (1); two β-agostic Y⋯(H–Si) interactions are observed for each C(SiHMe2)3 ligand in 2, giving six agostic interactions per yttrium(III) center.

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