Enantioselective self-assembly of chiralcalix[4]arene acid with amines
Literature Information
Yan-Song Zheng, Shu-Yun Ran, Yu-Jian Hu, Xian-Xian Liu
A chiralcalix[4]arene bearing L-2,3-dibenzoyltartaric acid groups at the lower rim was synthesized and could enantioselectively self-assemble to result in a gel or suspension only with one enantiomer of chiralamines; as revealed by electron microscopy, the resultant gel was of nanofibers with a high aspect ratio but the suspension was composed of nanospheres.
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