Relaxation rates for spirocyclohexyl nitroxyl radicals are suitable for interspin distance measurements at temperatures up to about 125 K
Literature Information
Velavan Kathirvelu, Christopher Smith, Christopher Parks, Md. Abdul Mannan, Yozo Miura, Keizo Takeshita, Sandra S. Eaton, Gareth R. Eaton
Between 65 and 175 K, nitroxyl radicals with spirocyclohexyl groups at the 2- and 6-positions of the piperidine ring exhibit spin echo dephasing rates that are slower than for nitroxyl radicals with 2,5-gem-dimethyl or 2,6-gem-dimethyl substituents that are currently used as spin labels, and are slow enough to permit DEER measurements at temperatures up to about 125 K for spin labels with analogous ring structures.
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Proceedings of the Society of Public Analysts and other Analytical Chemists
DOI: 10.1039/AN938630775A
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