Effect of solutes on the heterogeneous nucleation temperature of supercooled water: an experimental determination

Literature Information

Publication Date 2009-02-25
DOI 10.1039/B817585C
Impact Factor 3.676
Authors

P. W. Wilson, A. D. J. Haymet


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Abstract

We investigate the effect of solute concentration on the heterogeneous ice nucleation temperature (Thet) of aqueous solutions of both NaCl and D-glucose. An automatic lag time apparatus (ALTA) technique allows the dependence of Thet on solute concentration to be determined with statistical significance. Our results point to the solute-induced lowering of Thet being a factor of two times the equivalent melting point depression at any fixed concentration, the same factor reported for homogeneous nucleation experiments with small molecular weight solutes.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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