Synthesis and structural characterisation of a soluble, metastable indium(i) halide complex, [InBr(tmeda)]

Literature Information

Publication Date 2008-11-04
DOI 10.1039/B814658F
Impact Factor 6.222
Authors

Cameron Jones, Andreas Stasch


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Abstract

The first example of an indium(I) halide complex, [InBr(tmeda)], has been prepared by the reversible dissolution of InBr in a tmeda–toluene mixture. The structural characterisation of the metastable compound shows it to be monomeric with weak In⋯In interactions in the solid state. In solution, it decomposes to either InBr or [In2Br4(tmeda)2].

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