A snapshot of a coordination polymerself-assembly process: the crystallization of a metastable 3D network followed by the spontaneous transformation in water to a 2D pseudopolymorphic phase

Literature Information

Publication Date 2008-11-04
DOI 10.1039/B813222D
Impact Factor 6.222
Authors

Thierry Bataille, Ferdinando Costantino, Andrea Ienco, Annalisa Guerri, Fabio Marmottini, Stefano Midollini


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Abstract

A metastable copper(II) 3D hybrid with 4,4′-bipyridine (4,4′-bipy) and P,P′-diphenylethylenediphosphinate (pc2p2–) undergoes a spontaneous, quantitative, transformation to a stable 2D polymorphic species either spontaneously in water, or after thermal dehydration followed by hydration.

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DOI: 10.1039/AN943680115A

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Chemical Communications

Chemical Communications
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