Facile photoinduced charge separation through a cyanoacetylide bridge in a heterobimetallic Fe(ii)–Re(i) complex
Literature Information
Mark E. Smith, Emma L. Flynn, Mark A. Fox, Alexandre Trottier, Eckart Wrede, Dmitri S. Yufit, Judith A. K. Howard, Kate L. Ronayne, Michael Towrie, Anthony W. Parker, František Hartl, Paul J. Low
Photoinduced Fe-to-bpy charge transfer in [{Cp(dppe)Fe}(μ-CCCN){Re(CO)3(bpy)}]PF6 has been observed by ps-TRIR spectroscopy, supported by UV-Vis/IR spectroelectrochemistry and DFT calculations.
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Chemical Communications

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