Synthesis of 3-hydroxy-1-alkenylboronates viaphosphine stabilized borylzirconacyclopropenes‡
Literature Information
Alina Botvinik, Abraham Rubinstein, Morris Srebnik
Zirconacyclopropenylboronates can be stabilized to dimerization by complexation with tributylphosphine; the phosphine stabilized zirconacycle boronates react with aliphatic and aromatic ketones and aldehydes at C2 of the triple bond to give the previously unknown 3-hydroxyvinylboronates in 61–80% isolated yields.
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