Phase transition and conductive acceleration of phosphonium-cation-based room-temperature ionic liquid

Literature Information

Publication Date 2008-09-23
DOI 10.1039/B809309A
Impact Factor 6.222
Authors

Shiro Seki, Yasuhiro Umebayashi, Seiji Tsuzuki, Kikuko Hayamizu, Yo Kobayashi, Yasutaka Ohno, Takeshi Kobayashi, Yuichi Mita, Hajime Miyashiro, Nobuyuki Terada, Shin-ichi Ishiguro


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Abstract

An unusual ionic conduction phenomenon related to the phase transition of a novel phosphonium-cation-based room-temperature ionic liquid (RTIL) is reported; we found that in the phase change upon cooling, a clear increase in ionic conductivity was seen as the temperature was lowered, which differs from widely known conventional RTILs; clearly, our finding of abnormality of the correlation between temperature change and ionic conduction is the first observation in the electrolyte field.

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