Biaryl phosphite-oxazolines from hydroxyl aminoacid derivatives: highly efficient modular ligands for Ir-catalyzed hydrogenation of alkenes

Literature Information

Publication Date 2008-07-03
DOI 10.1039/B806891G
Impact Factor 6.222
Authors

Montserrat Diéguez, Javier Mazuela, Oscar Pàmies, J. Johan Verendel, Pher G. Andersson


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Abstract

High enantioselectivities and activities are achieved in the Ir-catalyzed hydrogenation of several unfunctionalized olefins using modular biaryl phosphite-oxazoline ligands from hydroxyl aminoacid derivatives; the presence of a biaryl phosphite group is crucial to this success.

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