Giant molecular spoked wheels in giant voids: two-dimensional molecular self-assembly goes big

Literature Information

Publication Date 2008-06-27
DOI 10.1039/B806444J
Impact Factor 6.222
Authors

Shenbin Lei, Dennis Mössinger, Hiroyoshi Kozuma, Koji Inukai, Mark Van der Auweraer, Frans C. De Schryver, Sigurd Höger, Yoshito Tobe, Steven De Feyter


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Abstract

We present here the formation of giant pores in surface-confined molecular networks of a triangular-shaped dehydrobenzo-[12]annulene derivative: the diameter of the pores reaches over 7 nm and the giant pores are used as templates to accommodate a giant molecular spoked wheel, which allows us to observe rotational and adsorption–desorption dynamics of single guest molecules.

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