Giant molecular spoked wheels in giant voids: two-dimensional molecular self-assembly goes big
Literature Information
Shenbin Lei, Dennis Mössinger, Hiroyoshi Kozuma, Koji Inukai, Mark Van der Auweraer, Frans C. De Schryver, Sigurd Höger, Yoshito Tobe, Steven De Feyter
We present here the formation of giant pores in surface-confined molecular networks of a triangular-shaped dehydrobenzo-[12]annulene derivative: the diameter of the pores reaches over 7 nm and the giant pores are used as templates to accommodate a giant molecular spoked wheel, which allows us to observe rotational and adsorption–desorption dynamics of single guest molecules.
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