Anti-Markovnikov hydroarylation of styrenes catalyzed by an in situ generated ruthenium complex
Literature Information
Rémi Martinez, Jean-Pierre Genet, Sylvain Darses
An efficient and practical catalytic system for the anti-Markovnikov ruthenium-catalyzed hydroarylation of styrenes with acetophenone, allowing a straightforward access to bibenzyl backbones, is described for the first time: this process, involving regioselective C–H bond activation, is complementary to a Friedel–Crafts type reaction giving the branched adduct.
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Chemical Communications

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