Electrochemically and photochemically active Palladium(ii) heterotopic metallacalix[3]arenes

Literature Information

Publication Date 2008-06-18
DOI 10.1039/B805705B
Impact Factor 6.222
Authors

Andrew Houlton, William Clegg, Ross W. Harrington, José Dobado, Francisco Santoyo-Gonzalez, Fatima Linares, M. Angustias Romero, Jorge A. R. Navarro


View Original

Abstract

The cyclic trinuclear system, [(en)3Pd3(4,7-phen)3]6+, undergoes a ligand exchange reaction with 5-R-2-hydroxypyrimidine derivatives (HRpymo; R = ethynylferrocene, 5-(dimethylamino)-N-(2-propynyl)-1-naphthalene sulfonamide) to give [(en)3Pd3(4,7-phen)2(Rpymo)]5+, functional supramolecular receptors of mononucleotides.

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Chemical Communications

Chemical Communications
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ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

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