Electrochemically and photochemically active Palladium(ii) heterotopic metallacalix[3]arenes
Literature Information
Andrew Houlton, William Clegg, Ross W. Harrington, José Dobado, Francisco Santoyo-Gonzalez, Fatima Linares, M. Angustias Romero, Jorge A. R. Navarro
The cyclic trinuclear system, [(en)3Pd3(4,7-phen)3]6+, undergoes a ligand exchange reaction with 5-R-2-hydroxypyrimidine derivatives (HRpymo; R = ethynylferrocene, 5-(dimethylamino)-N-(2-propynyl)-1-naphthalene sulfonamide) to give [(en)3Pd3(4,7-phen)2(Rpymo)]5+, functional supramolecular receptors of mononucleotides.
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![2,2'-{2,2-Propanediylbis[(2,6-dibromo-4,1-phenylene)oxy]}diethanol structure 2,2'-{2,2-Propanediylbis[(2,6-dibromo-4,1-phenylene)oxy]}diethanol structure](https://static.chemtradehub.com/structs/416/4162-45-2-b3d6.webp)