Intramolecularcation–π interactions control the conformation of nonrestricted (phenylalkyl)pyridines
Literature Information
Isabella Richter, Jusaku Minari, Philip Axe, John P. Lowe, Tony D. James, Kazuo Sakurai, Steven D. Bull, John S. Fossey
NOEsy and fluorescence spectroscopy reveal that conversion of conformationally flexible (phenylalkyl)pyridines into their corresponding N-methyl-pyridinium iodides results in intramolecular π-stacking.
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