Decarboxylative reduction of free aliphatic carboxylic acids by photogenerated cation radical

Literature Information

Publication Date 2007-10-17
DOI 10.1039/B714526H
Impact Factor 6.222
Authors

Yasuharu Yoshimi, Tatsuya Itou, Minoru Hatanaka


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Abstract

The decarboxylation of free carboxylic acids was effected by a photogenerated cation radical of phenanthrene to yield the reduction product in the presence of a thiol, which provides an alternative method to the Barton decarboxylation procedure for aliphatic acids such as N-Boc amino acids.

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