Base free lithium-organoaluminate and the gallium congener: potential precursors to heterometallic assemblies

Literature Information

Publication Date 2007-10-29
DOI 10.1039/B712240C
Impact Factor 6.222
Authors

Sanjay Singh, Jianfang Chai, Aritra Pal, Vojtech Jancik, Herbert W. Roesky, Regine Herbst-Irmer


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Abstract

The first examples of base free lithium-organoaluminate and the corresponding gallium compound [LM(Me)OLi]3 (M = Al (3), Ga (4); L = HC{C(Me)N-2,6-iPr2C6H3}2) have been prepared by the reaction of Li[N(SiMe3)2] with the corresponding metal hydroxides LM(Me)OH (M = Al (1), Ga(2)); the oxygen atom in the M–O–Li fragment exists as oxide ion and is involved in the central Li3O3 six-membered ring formation.

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