Synthesis and reactions of β-diketiminato divanadium(i) inverted-sandwich complexes

Literature Information

Publication Date 2007-10-19
DOI 10.1039/B711816C
Impact Factor 6.222
Authors

Yi-Chou Tsai, Po-Yang Wang, Kuan-Ming Lin, Shin-An Chen, Jin-Ming Chen


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Abstract

Reduction of VCl2(Nacnac) (Nacnac = HC(C(Me)NC6H3-iPr2)2) with KC8 in toluene leads to the formation of a toluene-bridged inverted-sandwich divanadium(I) complex, (µ-η6:η6-C7H8)[V(Nacnac)]2, which behaves as a source of V(Nacnac) and a multi-electron reductant in the two reactions studied in this report.

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