A Lewis-basic, dionio-substituted phosphane

Literature Information

Publication Date 2007-10-09
DOI 10.1039/B710923G
Impact Factor 6.222
Authors

Martyn P. Coles, Peter B. Hitchcock


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Abstract

Bis{guanidine} H2C{hpp}2 [hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine] reacts with PPhCl2 to generate the dionio-substituted phosphane, [H2C{hpp}2PPh]2+[Cl]–2 which, despite the formally dicationic phosphorus centre, forms an unprecedented coordination compound with platinum.

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