Fast, efficient Ru(iv)-catalysed regioselective allylation of indoles using allyl alcohol (without additives) under mild conditions

Literature Information

Publication Date 2007-10-15
DOI 10.1039/B710763C
Impact Factor 6.222
Authors

Alexey B. Zaitsev, Stefan Gruber, Paul S. Pregosin


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Abstract

The new Ru(IV) salt, [Ru(η3-C3H5)(Cp*)(CH3CN)2](PF6)2, is an excellent catalyst for the regioselective allylation of a variety of indole compounds using allyl alcohol as substrate; there are no co-catalysts required in this chemistry and the yields and reaction conditions are very favorable.

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