An unprecedented co-crystal including a cis-high-spin and a trans-low-spin FeII complex molecule

Literature Information

Publication Date 2007-10-09
DOI 10.1039/B710734J
Impact Factor 6.222
Authors

Nicolas Bréfuel, Carine Duhayon, Jean-Pierre Tuchagues


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Abstract

Two structurally and magnetically nonequivalent isomeric molecules, a cis-high-spin and a trans-low-spin isomer constitute the unit cell of a new iron(II) complex {cis-[FeLB5(NCS)2]·trans-[FeLB5(NCS)2]}·CH3OH, 1, (LB5 = N,N′-bis((2-N-methylimidazol-1-yl)methylene))-2,2-dimethylpropane-1,3-diamine); the synthesis, X-ray structure, and magnetic and Mössbauer study of this unique example of co-crystallised geometric, conformational and electronic isomers are reported.

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Back matter

Front/Back Matter

DOI: 10.1039/C2CP90175G

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