An unprecedented co-crystal including a cis-high-spin and a trans-low-spin FeII complex molecule
Literature Information
Nicolas Bréfuel, Carine Duhayon, Jean-Pierre Tuchagues
Two structurally and magnetically nonequivalent isomeric molecules, a cis-high-spin and a trans-low-spin isomer constitute the unit cell of a new iron(II) complex {cis-[FeLB5(NCS)2]·trans-[FeLB5(NCS)2]}·CH3OH, 1, (LB5 = N,N′-bis((2-N-methylimidazol-1-yl)methylene))-2,2-dimethylpropane-1,3-diamine); the synthesis, X-ray structure, and magnetic and Mössbauer study of this unique example of co-crystallised geometric, conformational and electronic isomers are reported.
Recommended Journals
Related Literature
Effect of hydrogen in controlling the structural orientation of ZnO:Ga:H as transparent conducting oxide films suitable for applications in stacked layer devices
Praloy Mondal, Debajyoti Das
DOI: 10.1039/C6CP03613A
Photoinduced electron transfer from quantum dots to TiO2: elucidating the involvement of excitonic and surface states
Saurabh Chauhan, David F. Watson
DOI: 10.1039/C6CP03813A
Anomalous system-size dependence of electrolytic cells with an electrified oil–water interface
Niels Boon, René van Roij
DOI: 10.1039/C5CP02945G
Effects of substituents on fluorometric detection of cyanide anions by indolium–coumarin dyads
Masaya Nakamura, Takayuki Hirai
DOI: 10.1039/C5CP03877D
Interaction of l-alanyl-l-valine and l-valyl-l-alanine with organic vapors: thermal stability of clathrates, sorption capacity and the change in the morphology of dipeptide films
Marat A. Ziganshin, Nadezhda S. Gubina, Alexander V. Gerasimov, Valery V. Gorbatchuk, Sufia A. Ziganshina, Anton P. Chuklanov, Anastas A. Bukharaev
DOI: 10.1039/C5CP03309H
Photodissociation of aniline N–H bonds in clusters of different nature
Viktoriya Poterya, Dana Nachtigallová, Jozef Lengyel, Michal Fárník
DOI: 10.1039/C5CP04485E
On the fractality of the Freundlich adsorption isotherm in equilibrium and non-equilibrium cases
Przemysław Borys, Zbigniew J. Grzywna
DOI: 10.1039/C6CP03356C
Vertical heterostructures of MoS2 and graphene nanoribbons grown by two-step chemical vapor deposition for high-gain photodetectors
Rozan Mohamad Yunus, Hiroko Endo
DOI: 10.1039/C5CP03958D
A molecular theory for optimal blue energy extraction by electrical double layer expansion
Alejandro Gallegos, Diannan Lu, Zheng Liu, Jianzhong Wu
DOI: 10.1039/C5CP03514G
Electronic properties of epitaxial cerium oxide films during controlled reduction and oxidation studied by resonant inelastic X-ray scattering
Lucia Amidani, Pieter Glatzel, Paola Luches
DOI: 10.1039/C6CP04407G
You might also like
What precautions should be taken when handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3)?
When handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3), safety go...
What is 4-(3,5-Difluorophenyl)aniline (CAS: 405058-00-6)?
4-(3,5-Difluorophenyl)aniline is an aromatic organic compound with the CAS numbe...
How is 5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid (CAS: 338982-07-3) typically synthesized?
5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid can ...
What is the market or research trend for 4-Benzylaniline hydrochloride (CAS: 6317-57-3)?
The market for 4-Benzylaniline hydrochloride (CAS: 6317-57-3) is steadily growin...
Is [3-(Diethylsulfamoyl)phenyl]boronic acid (CAS: 871329-58-7) safe?
[3-(Diethylsulfamoyl)phenyl]boronic acid is generally considered safe when handl...
What are the main uses of 3-Bromo-2,5-dimethoxyaniline (CAS: 115929-62-9)?
3-Bromo-2,5-dimethoxyaniline is mainly used in the pharmaceutical and chemical i...
What regulatory guidelines apply to N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7)?
N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7) is subject to ...
What industries use Carbamic acid, N-[(5S)-5,6-diamino-6-oxohexyl]-, 1,1-dimethylethyl ester (CAS: 24828-96-4)?
This compound is primarily used in the pharmaceutical industry for the synthesis...
How should 2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) be stored?
2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) sho...
What industries use Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9)?
Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9) is utilized in the pharma...
Source Journal
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry










![Methyl 3-({2'-[(E)-(hydroxyhydrazono)methyl]-4-biphenylyl}methyl)-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxylate structure Methyl 3-({2'-[(E)-(hydroxyhydrazono)methyl]-4-biphenylyl}methyl)-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxylate structure](https://static.chemtradehub.com/structs/149/1499167-72-4-034a.webp)

![6,7-Dihydro-5H-pyrrolo[1,2-a]imidazole-6-carboxylic acid structure 6,7-Dihydro-5H-pyrrolo[1,2-a]imidazole-6-carboxylic acid structure](https://static.chemtradehub.com/structs/136/1369160-12-2-6524.webp)

