Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane–borane adduct

Literature Information

Publication Date 2007-10-02
DOI 10.1039/B710475H
Impact Factor 6.222
Authors

Patrick Spies, Gerhard Erker, Gerald Kehr, Klaus Bergander, Roland Fröhlich, Stefan Grimme, Douglas W. Stephan


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Abstract

A four-membered cyclic intramolecular phosphane–borane adduct activates dihydrogen to yield the respective ethylene-bridged zwitterionic phosphonium–hydridoborate system, which reduces benzaldehyde.

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Chemical Communications

Chemical Communications
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