Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane–borane adduct
Literature Information
Patrick Spies, Gerhard Erker, Gerald Kehr, Klaus Bergander, Roland Fröhlich, Stefan Grimme, Douglas W. Stephan
A four-membered cyclic intramolecular phosphane–borane adduct activates dihydrogen to yield the respective ethylene-bridged zwitterionic phosphonium–hydridoborate system, which reduces benzaldehyde.
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