NO-disproportionation, promoted by Pd-cluster: formation and X-ray structure of Pd8(μ-CO)4(μ-OOCCMe3)8[μ-N(O)O–]4

Literature Information

Publication Date 2007-09-10
DOI 10.1039/B710230E
Impact Factor 6.222
Authors

Tatiana A. Stromnova, Oleg N. Shishilov, Andrei V. Churakov, Lyudmila G. Kuz'mina, Judith A. K. Howard


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Abstract

Interaction of Pd-clusters [Pd(CO)(OCOR)]n with NO was investigated, these Pd-clusters were found to promote the NO disproportionation into N2 and NO2− in mild conditions; an eight-nuclear palladium cluster Pd8(μ-CO)4(μ-OOCCMe3)8(μ-NO2)4 with a new type of structure and an uncommon set of ligands was characterized by X-ray diffraction analysis.

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