Tricarbonylmanganese(i)–lysozyme complex: a structurally characterized organometallic protein

Literature Information

Publication Date 2007-06-11
DOI 10.1039/B703887A
Impact Factor 6.222
Authors

Mathieu Razavet, Vincent Artero, Christine Cavazza, Yohan Oudart, Colette Lebrun, Juan Carlos Fontecilla-Camps, Marc Fontecave


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Abstract

The reaction of the new and structurally characterized covalent {Mn(CO)3(H2O)2}+–lysozyme adduct with NiS4 and NiN2S2 complexes generates binuclear Ni–Mn complexes; relevance to the reactivity of the protein-bound {Fe(CO)(CN)2} intermediate during maturation of [NiFe] hydrogenases is discussed.

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