Chirality induction in a cation-driven assembly using a crowned metalloporphyrin
Literature Information
Yusuke Ishii, Yoshiei Soeda, Yuji Kubo
15-Crown-5-appended metalloporphyrin causes a K+-driven self-organization to bind a bifunctional guest ditopically, thereby allowing the circular dichroism (CD) detection of chirality induced in the ensemble when chiral amines are employed as the guest; the chiroptical properties are discussed.
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