Aryl bromide/triflate selectivities reveal mechanistic divergence in palladium-catalysed couplings; the Suzuki–Miyaura anomaly

Literature Information

Publication Date 2007-04-05
DOI 10.1039/B701517H
Impact Factor 6.222
Authors

Gustavo Espino, Almira Kurbangalieva, John M. Brown


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Abstract

In palladium-catalysed cross-coupling reactions, the outcome of competition between aryl bromides and aryl triflates depends on the nucleophilic partner; Suzuki couplings with R–B generally follow a different pattern from other R–M species.

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