Copper-catalyzed oxidative desulfurization–oxygenation of thiocarbonyl compounds using molecular oxygen: an efficient method for the preparation of oxygen isotopically labeled carbonyl compounds

Literature Information

Publication Date 2007-03-08
DOI 10.1039/B701048F
Impact Factor 6.222
Authors

Fumitoshi Shibahara, Aiko Suenami, Atsunori Yoshida, Toshiaki Murai


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Abstract

A novel copper-catalyzed oxidative desulfurization reaction of thiocarbonyl compounds, using molecular oxygen as an oxidant and leading to formation of carbonyl compounds, has been developed, and the utility of the process is demonstrated by its application to the preparation of a carbonyl-18O labeled sialic acid derivative.

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